Triple
T21066471
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Debye–Hückel theory |
E518985
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object | Pitzer model |
—
|
NE NERFINISHED |
How this triple was built (3 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Pitzer model | Statement: [Debye–Hückel theory, relatedTo, Pitzer model]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Pitzer model Context triple: [Debye–Hückel theory, relatedTo, Pitzer model]
-
A.
Debye–Hückel theory
Debye–Hückel theory is a foundational model in physical chemistry that explains how electrostatic interactions between ions in solution affect properties such as activity coefficients and equilibrium behavior in electrolytes.
-
B.
Flory–Huggins solution theory
Flory–Huggins solution theory is a thermodynamic model that describes the mixing behavior and phase separation of polymer solutions by accounting for the size difference between polymer chains and solvent molecules.
-
C.
Gibbs–Duhem equation
The Gibbs–Duhem equation is a fundamental thermodynamic relation that links changes in chemical potential, temperature, and pressure for multicomponent systems, ensuring consistency among intensive variables.
-
D.
Kirkwood–Buff solution theory
Kirkwood–Buff solution theory is a statistical mechanical framework that relates microscopic pair correlation functions to macroscopic thermodynamic properties of solutions, widely used to analyze solvation and mixture behavior.
-
E.
Temkin adsorption isotherm
The Temkin adsorption isotherm is a model in surface chemistry that describes adsorption by assuming adsorbate–adsorbent interactions cause a linear decrease in adsorption energy with increasing surface coverage.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Pitzer model Target entity description: The Pitzer model is a thermodynamic framework used to accurately describe activity coefficients and interactions in electrolyte solutions, especially at high ionic strengths where simpler models like Debye–Hückel fail.
-
A.
Debye–Hückel theory
Debye–Hückel theory is a foundational model in physical chemistry that explains how electrostatic interactions between ions in solution affect properties such as activity coefficients and equilibrium behavior in electrolytes.
-
B.
Flory–Huggins solution theory
Flory–Huggins solution theory is a thermodynamic model that describes the mixing behavior and phase separation of polymer solutions by accounting for the size difference between polymer chains and solvent molecules.
-
C.
Gibbs–Duhem equation
The Gibbs–Duhem equation is a fundamental thermodynamic relation that links changes in chemical potential, temperature, and pressure for multicomponent systems, ensuring consistency among intensive variables.
-
D.
Kirkwood–Buff solution theory
Kirkwood–Buff solution theory is a statistical mechanical framework that relates microscopic pair correlation functions to macroscopic thermodynamic properties of solutions, widely used to analyze solvation and mixture behavior.
-
E.
Temkin adsorption isotherm
The Temkin adsorption isotherm is a model in surface chemistry that describes adsorption by assuming adsorbate–adsorbent interactions cause a linear decrease in adsorption energy with increasing surface coverage.
- F. None of above. chosen
Provenance (2 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69e0b505ef108190b25dd4033e2ff7eb |
completed | April 16, 2026, 10:08 a.m. |
| NER | Named-entity recognition | batch_69e6feb455fc81909cc63fa0e87b6a35 |
completed | April 21, 2026, 4:36 a.m. |
Created at: April 16, 2026, 2:45 p.m.