Triple
T210290
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Franck–Condon principle |
E4700
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object |
Huang–Rhys factor
The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
|
E27438
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Huang–Rhys factor | Statement: [Franck–Condon principle, relatedTo, Huang–Rhys factor]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Huang–Rhys factor Context triple: [Franck–Condon principle, relatedTo, Huang–Rhys factor]
-
A.
Franck–Condon principle
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
-
C.
Feynman–Hellmann theorem
The Feynman–Hellmann theorem is a result in quantum mechanics that relates the derivative of an energy eigenvalue with respect to a parameter in the Hamiltonian to the expectation value of the corresponding derivative of the Hamiltonian.
-
D.
Born–Huang expansion
The Born–Huang expansion is a quantum mechanical method that systematically improves upon the Born–Oppenheimer approximation by including couplings between electronic and nuclear motions in molecular systems.
-
E.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Huang–Rhys factor Triple: [Franck–Condon principle, relatedTo, Huang–Rhys factor]
Generated description
The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Huang–Rhys factor Target entity description: The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
-
A.
Franck–Condon principle
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
-
C.
Feynman–Hellmann theorem
The Feynman–Hellmann theorem is a result in quantum mechanics that relates the derivative of an energy eigenvalue with respect to a parameter in the Hamiltonian to the expectation value of the corresponding derivative of the Hamiltonian.
-
D.
Born–Huang expansion
The Born–Huang expansion is a quantum mechanical method that systematically improves upon the Born–Oppenheimer approximation by including couplings between electronic and nuclear motions in molecular systems.
-
E.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69a2575cb1dc8190a01ad332426dc339 |
completed | Feb. 28, 2026, 2:47 a.m. |
| NER | Named-entity recognition | batch_69a25c2ead8481909996042efcae5e9d |
completed | Feb. 28, 2026, 3:08 a.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69a33e3dc3008190a021d1b18438b773 |
completed | Feb. 28, 2026, 7:13 p.m. |
| NEDg | Description generation | batch_69a33e9b9db0819087e95e2734807ce1 |
completed | Feb. 28, 2026, 7:14 p.m. |
| NED2 | Entity disambiguation (via description) | batch_69a33ef2d5208190ba605b270f7ce5df |
completed | Feb. 28, 2026, 7:16 p.m. |
Created at: Feb. 28, 2026, 2:52 a.m.