Triple

T210286
Position Surface form Disambiguated ID Type / Status
Subject Franck–Condon principle E4700 entity
Predicate relatedTo P37 FINISHED
Object Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
E27647 NE FINISHED

How this triple was built (4 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Herzberg–Teller approximation | Statement: [Franck–Condon principle, relatedTo, Herzberg–Teller approximation]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07
Target entity: Herzberg–Teller approximation
Context triple: [Franck–Condon principle, relatedTo, Herzberg–Teller approximation]
  • A. Born–Oppenheimer approximation
    The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
  • B. Rayleigh–Schrödinger perturbation theory
    Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
  • C. Huang–Rhys factor
    The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
  • D. The Nature of the Chemical Bond
    The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
  • E. Feynman–Hellmann theorem
    The Feynman–Hellmann theorem is a result in quantum mechanics that relates the derivative of an energy eigenvalue with respect to a parameter in the Hamiltonian to the expectation value of the corresponding derivative of the Hamiltonian.
  • F. None of above. chosen
  • G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg Description generation gpt-5.1
Instruction
Generate a one-sentence description of the target entity. 
You are given a context triple in the form (subject, predicate, object), where the object is the target entity. 
# Instructions
Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. 
Avoid repeating the information from the triple, unless really essential.
# Response Format
Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Herzberg–Teller approximation
Triple: [Franck–Condon principle, relatedTo, Herzberg–Teller approximation]
Generated description
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
NED2 Entity disambiguation (via description) gpt-5-mini-2025-08-07
Target entity: Herzberg–Teller approximation
Target entity description: The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • A. Born–Oppenheimer approximation
    The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
  • B. Rayleigh–Schrödinger perturbation theory
    Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
  • C. Huang–Rhys factor
    The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
  • D. The Nature of the Chemical Bond
    The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
  • E. Feynman–Hellmann theorem
    The Feynman–Hellmann theorem is a result in quantum mechanics that relates the derivative of an energy eigenvalue with respect to a parameter in the Hamiltonian to the expectation value of the corresponding derivative of the Hamiltonian.
  • F. None of above. chosen

Provenance (5 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69a2575cb1dc8190a01ad332426dc339 completed Feb. 28, 2026, 2:47 a.m.
NER Named-entity recognition batch_69a25c2ead8481909996042efcae5e9d completed Feb. 28, 2026, 3:08 a.m.
NED1 Entity disambiguation (via context triple) batch_69a3441cc15c8190910b1b9e5dbb4910 completed Feb. 28, 2026, 7:38 p.m.
NEDg Description generation batch_69a344e390f4819090ec79beb681310a completed Feb. 28, 2026, 7:41 p.m.
NED2 Entity disambiguation (via description) batch_69a34551abac8190a1d3f2fc3f783c71 completed Feb. 28, 2026, 7:43 p.m.
Created at: Feb. 28, 2026, 2:52 a.m.