Triple
T210268
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Franck–Condon principle |
E4700
|
entity |
| Predicate | usesConcept |
P531
|
FINISHED |
| Object |
Franck–Condon factors
Franck–Condon factors are quantitative measures of the overlap between vibrational wavefunctions in different electronic states, determining the relative intensities of vibronic transitions in molecules.
|
E4700
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Franck–Condon factors | Statement: [Franck–Condon principle, usesConcept, Franck–Condon factors]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Franck–Condon factors Context triple: [Franck–Condon principle, usesConcept, Franck–Condon factors]
-
A.
Franck–Condon principle
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
C.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
-
D.
Einstein coefficients
Einstein coefficients are parameters in quantum theory that quantify the probabilities of absorption, spontaneous emission, and stimulated emission of radiation by atoms or molecules.
-
E.
The Nature of the Chemical Bond
The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Franck–Condon factors Triple: [Franck–Condon principle, usesConcept, Franck–Condon factors]
Generated description
Franck–Condon factors are quantitative measures of the overlap between vibrational wavefunctions in different electronic states, determining the relative intensities of vibronic transitions in molecules.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Franck–Condon factors Target entity description: Franck–Condon factors are quantitative measures of the overlap between vibrational wavefunctions in different electronic states, determining the relative intensities of vibronic transitions in molecules.
-
A.
Franck–Condon principle
chosen
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
C.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
-
D.
Einstein coefficients
Einstein coefficients are parameters in quantum theory that quantify the probabilities of absorption, spontaneous emission, and stimulated emission of radiation by atoms or molecules.
-
E.
The Nature of the Chemical Bond
The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
- F. None of above.
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69a2575cb1dc8190a01ad332426dc339 |
completed | Feb. 28, 2026, 2:47 a.m. |
| NER | Named-entity recognition | batch_69a25c2ead8481909996042efcae5e9d |
completed | Feb. 28, 2026, 3:08 a.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69a338e8432081909c1b924250751022 |
completed | Feb. 28, 2026, 6:50 p.m. |
| NEDg | Description generation | batch_69a339955c1081909ab38da591b836cf |
completed | Feb. 28, 2026, 6:53 p.m. |
| NED2 | Entity disambiguation (via description) | batch_69a33a1d394c8190a9e1d686e20f1ade |
completed | Feb. 28, 2026, 6:55 p.m. |
Created at: Feb. 28, 2026, 2:52 a.m.