Triple
T21011995
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | On the Equilibrium of Heterogeneous Substances |
E517571
|
entity |
| Predicate | introducedConcept |
P201
|
FINISHED |
| Object | Gibbs–Duhem equation |
—
|
NE NERFINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Gibbs–Duhem equation | Statement: [On the Equilibrium of Heterogeneous Substances, introducedConcept, Gibbs–Duhem equation]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Gibbs–Duhem equation Context triple: [On the Equilibrium of Heterogeneous Substances, introducedConcept, Gibbs–Duhem equation]
-
A.
Gibbs–Duhem equation
chosen
The Gibbs–Duhem equation is a fundamental thermodynamic relation that links changes in chemical potential, temperature, and pressure for multicomponent systems, ensuring consistency among intensive variables.
-
B.
Gibbs phase rule
The Gibbs phase rule is a fundamental thermodynamic principle that relates the number of components and phases in a system to its degrees of freedom, determining how many variables can be independently varied without changing the number of phases in equilibrium.
-
C.
Clausius–Clapeyron relation
The Clausius–Clapeyron relation is a fundamental thermodynamic equation that describes how the pressure and temperature of a phase transition, such as boiling or condensation, are related.
-
D.
Maxwell relations
The Maxwell relations are a set of thermodynamic equations derived from the equality of mixed second derivatives of thermodynamic potentials, linking measurable quantities like temperature, pressure, entropy, and volume.
-
E.
Debye–Hückel theory
Debye–Hückel theory is a foundational model in physical chemistry that explains how electrostatic interactions between ions in solution affect properties such as activity coefficients and equilibrium behavior in electrolytes.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (2 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69e0b50192308190a284fcc89dd23a49 |
completed | April 16, 2026, 10:08 a.m. |
| NER | Named-entity recognition | batch_69e6fc40f91c81908c9b6d99869de7aa |
completed | April 21, 2026, 4:25 a.m. |
Created at: April 16, 2026, 1:53 p.m.