Triple
T19066348
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Corey–Kim oxidation |
E466667
|
entity |
| Predicate | relatedTo |
P37
|
FINISHED |
| Object |
Swern oxidation
Swern oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones under mild, low-temperature conditions using dimethyl sulfoxide (DMSO) and an activating agent.
|
E1356971
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Swern oxidation | Statement: [Corey–Kim oxidation, relatedTo, Swern oxidation]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Swern oxidation Context triple: [Corey–Kim oxidation, relatedTo, Swern oxidation]
-
A.
Corey–Kim oxidation
Corey–Kim oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones using N-chlorosuccinimide and dimethyl sulfide under mild conditions.
-
B.
Shi epoxidation
Shi epoxidation is an asymmetric organocatalytic reaction that converts alkenes to chiral epoxides using a fructose-derived ketone catalyst and an oxidant such as oxone.
-
C.
Barton–McCombie deoxygenation
Barton–McCombie deoxygenation is an organic chemistry reaction that converts alcohols into the corresponding hydrocarbons via radical-mediated removal of the hydroxyl group.
-
D.
Heck reaction
The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
-
E.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: Swern oxidation Triple: [Corey–Kim oxidation, relatedTo, Swern oxidation]
Generated description
Swern oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones under mild, low-temperature conditions using dimethyl sulfoxide (DMSO) and an activating agent.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Swern oxidation Target entity description: Swern oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones under mild, low-temperature conditions using dimethyl sulfoxide (DMSO) and an activating agent.
-
A.
Corey–Kim oxidation
Corey–Kim oxidation is an organic chemistry reaction that converts primary and secondary alcohols into aldehydes and ketones using N-chlorosuccinimide and dimethyl sulfide under mild conditions.
-
B.
Shi epoxidation
Shi epoxidation is an asymmetric organocatalytic reaction that converts alkenes to chiral epoxides using a fructose-derived ketone catalyst and an oxidant such as oxone.
-
C.
Barton–McCombie deoxygenation
Barton–McCombie deoxygenation is an organic chemistry reaction that converts alcohols into the corresponding hydrocarbons via radical-mediated removal of the hydroxyl group.
-
D.
Heck reaction
The Heck reaction is a palladium-catalyzed cross-coupling between alkenes and aryl or vinyl halides, widely used in organic synthesis to form carbon–carbon bonds.
-
E.
Norrish reaction
The Norrish reaction is a photochemical process in organic chemistry involving the cleavage and rearrangement of carbonyl compounds under ultraviolet light, fundamental to understanding photodegradation and radical mechanisms.
- F. None of above. chosen
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69d8dd04f4488190b1121cc53ef2bfd6 |
completed | April 10, 2026, 11:20 a.m. |
| NER | Named-entity recognition | batch_69e5e198621481908618f65dd01746fc |
completed | April 20, 2026, 8:19 a.m. |
| NED1 | Entity disambiguation (via context triple) | batch_6a05d3586fc88190b7e48c4afb767a2a |
completed | May 14, 2026, 1:51 p.m. |
| NEDg | Description generation | batch_6a05d430aabc8190bdf30a16700e2476 |
completed | May 14, 2026, 1:54 p.m. |
| NED2 | Entity disambiguation (via description) | batch_6a05d4e41f108190a2d7a3a60d1e3b87 |
completed | May 14, 2026, 1:57 p.m. |
Created at: April 10, 2026, 12:03 p.m.