Triple
T1565487
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Brillouin–Wigner perturbation theory |
E33422
|
entity |
| Predicate | relatedConcept |
P37
|
FINISHED |
| Object |
quasi-degenerate perturbation theory
Quasi-degenerate perturbation theory is a refinement of standard perturbation methods in quantum mechanics designed to accurately treat systems with closely spaced (nearly degenerate) energy levels.
|
E33422
|
NE FINISHED |
How this triple was built (4 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: quasi-degenerate perturbation theory | Statement: [Brillouin–Wigner perturbation theory, relatedConcept, quasi-degenerate perturbation theory]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: quasi-degenerate perturbation theory Context triple: [Brillouin–Wigner perturbation theory, relatedConcept, quasi-degenerate perturbation theory]
-
A.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
-
B.
Brillouin–Wigner perturbation theory
Brillouin–Wigner perturbation theory is a formulation of quantum mechanical perturbation theory that uses an energy-dependent effective Hamiltonian to obtain improved approximations to eigenvalues and eigenstates.
-
C.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
D.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
E.
Condon approximation
The Condon approximation is a simplifying assumption in molecular spectroscopy that treats electronic transition dipole moments as independent of nuclear coordinates, enabling easier calculation of vibronic transition intensities.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NEDg
Description generation
gpt-5.1
Instruction
Generate a one-sentence description of the target entity. You are given a context triple in the form (subject, predicate, object), where the object is the target entity. # Instructions Use the triple to infer relevant information about the entity. Describe the entity based on what is most defining, well-known. Avoid repeating the information from the triple, unless really essential. # Response Format Return only the sentence: "Description: [one-sentence description of the target entity]"
Input
Entity: quasi-degenerate perturbation theory Triple: [Brillouin–Wigner perturbation theory, relatedConcept, quasi-degenerate perturbation theory]
Generated description
Quasi-degenerate perturbation theory is a refinement of standard perturbation methods in quantum mechanics designed to accurately treat systems with closely spaced (nearly degenerate) energy levels.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: quasi-degenerate perturbation theory Target entity description: Quasi-degenerate perturbation theory is a refinement of standard perturbation methods in quantum mechanics designed to accurately treat systems with closely spaced (nearly degenerate) energy levels.
-
A.
Rayleigh–Schrödinger perturbation theory
Rayleigh–Schrödinger perturbation theory is a fundamental method in quantum mechanics for approximating the energies and states of a system by treating interactions as small corrections to an exactly solvable problem.
-
B.
Brillouin–Wigner perturbation theory
chosen
Brillouin–Wigner perturbation theory is a formulation of quantum mechanical perturbation theory that uses an energy-dependent effective Hamiltonian to obtain improved approximations to eigenvalues and eigenstates.
-
C.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
D.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
E.
Condon approximation
The Condon approximation is a simplifying assumption in molecular spectroscopy that treats electronic transition dipole moments as independent of nuclear coordinates, enabling easier calculation of vibronic transition intensities.
- F. None of above.
Provenance (5 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69a885f11b048190935025a035302715 |
completed | March 4, 2026, 7:20 p.m. |
| NER | Named-entity recognition | batch_69aa621242188190a7e1deeada7688d8 |
completed | March 6, 2026, 5:11 a.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69ad3719dfdc819085511f96f9f92dba |
completed | March 8, 2026, 8:45 a.m. |
| NEDg | Description generation | batch_69ad37d59e94819085504ea25dfa8311 |
completed | March 8, 2026, 8:48 a.m. |
| NED2 | Entity disambiguation (via description) | batch_69ad382b126c8190a308415bd6c4264b |
completed | March 8, 2026, 8:49 a.m. |
Created at: March 4, 2026, 7:27 p.m.