Triple

T1295673
Position Surface form Disambiguated ID Type / Status
Subject Herzberg–Teller approximation E27647 entity
Predicate refines P6555 FINISHED
Object Franck–Condon approximation E4700 NE FINISHED

How this triple was built (2 steps)

Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.

NER Named-entity recognition gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Franck–Condon approximation | Statement: [Herzberg–Teller approximation, refines, Franck–Condon approximation]
NED1 Entity disambiguation (via context triple) gpt-5-mini-2025-08-07 
Target entity: Franck–Condon approximation
Context triple: [Herzberg–Teller approximation, refines, Franck–Condon approximation]
  • A. Franck–Condon principle chosen
    The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
  • B. Born–Oppenheimer approximation
    The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
  • C. Herzberg–Teller approximation
    The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
  • D. Condon approximation
    The Condon approximation is a simplifying assumption in molecular spectroscopy that treats electronic transition dipole moments as independent of nuclear coordinates, enabling easier calculation of vibronic transition intensities.
  • E. Huang–Rhys factor
    The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
  • F. None of above.
  • G. Unsure - the case is ambiguous/there is not enough information to decide.

Provenance (3 batches)

The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.

Step Stage Batch ID Status When
creating Elicitation batch_69a496d6682881909ba658f1c1e0e2b0 completed March 1, 2026, 7:43 p.m.
NER Named-entity recognition batch_69a4c0f4031481908f5e3a53d8a72929 completed March 1, 2026, 10:43 p.m.
NED1 Entity disambiguation (via context triple) batch_69acbae7182081908b7045a15a2275d8 completed March 7, 2026, 11:55 p.m.
Created at: March 1, 2026, 7:51 p.m.