Triple
T1295672
| Position | Surface form | Disambiguated ID | Type / Status |
|---|---|---|---|
| Subject | Herzberg–Teller approximation |
E27647
|
entity |
| Predicate | refines |
P6555
|
FINISHED |
| Object | Franck–Condon principle |
E4700
|
NE FINISHED |
How this triple was built (2 steps)
Every LLM step that produced this triple, in pipeline order — named-entity classification, the disambiguation choices (the exact options shown, with the pick highlighted), and the generated description. The batch + timestamp of each is in the Provenance table below.
NER
Named-entity recognition
gpt-5-mini
Instruction
Given a phrase, classify it is english named entity (e.g., persons, organizations, works of art) in Latin script, or not (e.g., literals, dates, URLs, verbose phrases). For disambiguation, the statement where the phrase occurs as object is also given. Please return a JSON object with `phrase` (string, the phrase being analyzed) and `is_ne` (boolean, indicating whether the phrase is a Named Entity).
Input
Phrase: Franck–Condon principle | Statement: [Herzberg–Teller approximation, refines, Franck–Condon principle]
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Franck–Condon principle Context triple: [Herzberg–Teller approximation, refines, Franck–Condon principle]
-
A.
Franck–Condon principle
chosen
The Franck–Condon principle is a rule in molecular spectroscopy that explains the intensity distribution of vibronic transitions by assuming electronic transitions occur much faster than nuclear motion, making vertical transitions between vibrational states most probable.
-
B.
Born–Oppenheimer approximation
The Born–Oppenheimer approximation is a fundamental method in molecular quantum mechanics that simplifies calculations by treating nuclear motion as much slower than electronic motion, allowing their behaviors to be separated.
-
C.
Herzberg–Teller approximation
The Herzberg–Teller approximation is a refinement in molecular spectroscopy that accounts for vibronic coupling by allowing electronic transition dipole moments to depend on nuclear coordinates, explaining intensity in otherwise forbidden transitions.
-
D.
Stark effect
The Stark effect is the splitting and shifting of atomic or molecular spectral lines caused by an external electric field.
-
E.
Huang–Rhys factor
The Huang–Rhys factor is a dimensionless parameter in solid-state and molecular spectroscopy that quantifies the strength of electron–phonon (vibronic) coupling during electronic transitions.
- F. None of above.
- G. Unsure - the case is ambiguous/there is not enough information to decide.
Provenance (3 batches)
The batch behind each pipeline step, in order, with when it ran. Timestamps are batch-level — stages were processed in waves, so the object chain (NER → NED1 → NEDg → NED2) reads in order, but predicate / elicitation batches can sit in a different wave.
| Step | Stage | Batch ID | Status | When |
|---|---|---|---|---|
| creating | Elicitation | batch_69a496d6682881909ba658f1c1e0e2b0 |
completed | March 1, 2026, 7:43 p.m. |
| NER | Named-entity recognition | batch_69a4c0f4031481908f5e3a53d8a72929 |
completed | March 1, 2026, 10:43 p.m. |
| NED1 | Entity disambiguation (via context triple) | batch_69acb300d3a0819081a9d19ea1fbdfe2 |
completed | March 7, 2026, 11:21 p.m. |
Created at: March 1, 2026, 7:51 p.m.