stereochemicalOutcome
P109438
predicate
Indicates the specific three-dimensional spatial arrangement of atoms or groups in the product(s) that results from a chemical reaction or transformation.
All labels observed (2)
| Label | Occurrences |
|---|---|
| stereochemicalOutcome canonical | 14 |
| stereochemicalFeature | 3 |
Description generation (PDg)
The one-sentence description above was generated by prompting gpt-5.1 with the predicate name and this instruction.
Instruction
Given a predicate that represents a relationship or action between entities, generate a one-sentence description explaining its meaning. # Instructions Focus on describing the relationship, not the entities themselves. # Response Format Begin the description with \' Indicates...\'
Input
Predicate: stereochemicalOutcome
Generated description
Indicates the specific three-dimensional spatial arrangement of atoms or groups in the product(s) that results from a chemical reaction or transformation.
Sample triples (17)
| Subject | Object |
|---|---|
| Sharpless epoxidation | enantioselective ⓘ |
| Sharpless epoxidation | asymmetric ⓘ |
| Sharpless asymmetric dihydroxylation | syn addition ⓘ |
| Barton reaction | can proceed with partial loss of stereochemistry at radical center ⓘ |
| Barton–McCombie deoxygenation | often leads to loss of stereochemistry at carbon center ⓘ |
| Eschenmoser–Claisen rearrangement | chirality transfer from allylic center ⓘ |
| Corey–Winter olefin synthesis | stereospecific ⓘ |
| Corey–Winter olefin synthesis | retention of relative configuration of the diol ⓘ |
| Corey–Chaykovsky reagent | stereospecific epoxide formation ⓘ |
| Corey–Chaykovsky reagent | retention of configuration at carbonyl carbon ⓘ |
| Robinson annulation reaction | creates stereocenters ⓘ |
| Brown hydroboration | retention of relative configuration ⓘ |
| Evans auxiliary-based asymmetric synthesis | products with high enantiomeric excess after auxiliary removal ⓘ |
| Diels–Alder reaction | suprafacial on diene via predicate surface "stereochemicalFeature" ⓘ |
| Diels–Alder reaction | suprafacial on dienophile via predicate surface "stereochemicalFeature" ⓘ |
| Overman rearrangement | stereospecific under appropriate conditions ⓘ |
| Overman rearrangement | allylic configuration can be transferred to nitrogen-bearing center via predicate surface "stereochemicalFeature" ⓘ |