Statements (46)
| Predicate | Object |
|---|---|
| gptkbp:instance_of |
gptkb:chemical_compound
|
| gptkbp:activities |
involves oxidative addition
involves reductive elimination |
| gptkbp:application |
pharmaceutical chemistry
synthesis of natural products |
| gptkbp:discovered_by |
gptkb:John_Pauson
Shinichi Khand |
| gptkbp:dividend_yield |
can be optimized
varies with conditions |
| gptkbp:first_described_by |
gptkb:1970
|
| gptkbp:historical_significance |
contributed to organometallic chemistry development
important in synthetic methodology |
| https://www.w3.org/2000/01/rdf-schema#label |
Pauson– Khand reaction
|
| gptkbp:involves |
gptkb:chemical_compound
gptkb:carbon_monoxide alkyne |
| gptkbp:is_studied_in |
gptkb:academic_research
industrial applications |
| gptkbp:notable_work |
mechanistic studies
development of new catalysts applications in material science improvement of reaction conditions exploration of substrate scope |
| gptkbp:produced_by |
cyclopentenone
|
| gptkbp:products |
cyclohexene derivatives
cyclopentene derivatives fused ring systems |
| gptkbp:related_to |
alkyne metathesis
metal-catalyzed reactions |
| gptkbp:research_areas |
organometallic chemistry
synthetic organic chemistry |
| gptkbp:safety_features |
toxic gases involved
high pressure equipment required |
| gptkbp:type |
cyclization reaction
|
| gptkbp:used_in |
organic synthesis
|
| gptkbp:variant |
Pauson-Khand-type reactions
modified Pauson-Khand reactions |
| gptkbp:was_a_catalyst_for |
transition metal catalyst
|
| gptkbp:was_a_response_to |
high pressure
high temperature addition reaction cycloaddition reaction decarbonylation reaction |
| gptkbp:bfsParent |
gptkb:Corey–_Ziegler–_Pauson_reaction
gptkb:Corey–_Ziegler–_Ziegler–_Pauson_reaction |
| gptkbp:bfsLayer |
6
|