Organotransition Metal Chemistry: From Bonding to Catalysis
E1004257
"Organotransition Metal Chemistry: From Bonding to Catalysis" is a comprehensive graduate-level textbook that systematically develops the principles of organometallic bonding and reactivity with a strong emphasis on their applications in homogeneous catalysis.
All labels observed (1)
| Label | Occurrences |
|---|---|
| Organotransition Metal Chemistry: From Bonding to Catalysis canonical | 1 |
How this entity was disambiguated
This entity first appeared as the object of triple T12816771 — resolving that mention is where its identity was fixed. The disambiguator weighed these candidate entities and picked the highlighted one (or “None”, minting a new entity). This is how homonymy is resolved: the same surface form can point to different entities.
NED1
Entity disambiguation (via context triple)
gpt-5-mini-2025-08-07
Target entity: Organotransition Metal Chemistry: From Bonding to Catalysis Context triple: [John F. Hartwig, hasWritten, Organotransition Metal Chemistry: From Bonding to Catalysis]
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A.
Advanced Inorganic Chemistry (with F. Albert Cotton)
Advanced Inorganic Chemistry (with F. Albert Cotton) is a seminal graduate-level textbook that systematically presents the principles, structures, bonding, and reactivity of inorganic compounds and has long been a standard reference in the field.
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B.
Chemistry of Frontier Orbitals
"Chemistry of Frontier Orbitals" is a seminal work by Kenichi Fukui that develops and applies frontier molecular orbital theory to explain and predict the course of chemical reactions.
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C.
Supramolecular Chemistry: Concepts and Perspectives
Supramolecular Chemistry: Concepts and Perspectives is a foundational book by Nobel laureate Jean-Marie Lehn that systematically introduces the principles, concepts, and applications of supramolecular chemistry and molecular recognition.
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D.
Breslow intermediate in organocatalysis
The Breslow intermediate in organocatalysis is a transient nucleophilic carbene-derived species central to thiamine- and N-heterocyclic carbene-catalyzed umpolung reactions of carbonyl compounds.
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E.
The Nature of the Chemical Bond
The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
- F. None of above. chosen
- G. Unsure - the case is ambiguous/there is not enough information to decide.
NED2
Entity disambiguation (via description)
gpt-5-mini-2025-08-07
Target entity: Organotransition Metal Chemistry: From Bonding to Catalysis Target entity description: "Organotransition Metal Chemistry: From Bonding to Catalysis" is a comprehensive graduate-level textbook that systematically develops the principles of organometallic bonding and reactivity with a strong emphasis on their applications in homogeneous catalysis.
-
A.
Advanced Inorganic Chemistry (with F. Albert Cotton)
Advanced Inorganic Chemistry (with F. Albert Cotton) is a seminal graduate-level textbook that systematically presents the principles, structures, bonding, and reactivity of inorganic compounds and has long been a standard reference in the field.
-
B.
Chemistry of Frontier Orbitals
"Chemistry of Frontier Orbitals" is a seminal work by Kenichi Fukui that develops and applies frontier molecular orbital theory to explain and predict the course of chemical reactions.
-
C.
Supramolecular Chemistry: Concepts and Perspectives
Supramolecular Chemistry: Concepts and Perspectives is a foundational book by Nobel laureate Jean-Marie Lehn that systematically introduces the principles, concepts, and applications of supramolecular chemistry and molecular recognition.
-
D.
Breslow intermediate in organocatalysis
The Breslow intermediate in organocatalysis is a transient nucleophilic carbene-derived species central to thiamine- and N-heterocyclic carbene-catalyzed umpolung reactions of carbonyl compounds.
-
E.
The Nature of the Chemical Bond
The Nature of the Chemical Bond is a landmark chemistry book by Linus Pauling that systematically explains chemical bonding using quantum mechanics and became one of the most influential scientific texts of the 20th century.
- F. None of above. chosen
Statements (46)
| Predicate | Object |
|---|---|
| instanceOf |
graduate-level textbook
ⓘ
scientific book ⓘ textbook ⓘ |
| appliesTo |
design of homogeneous catalysts
ⓘ
fine chemical synthesis ⓘ industrial catalytic processes ⓘ polymerization catalysis ⓘ |
| educationalLevel | graduate ⓘ |
| emphasizes |
homogeneous catalytic processes
ⓘ
mechanistic understanding of catalysis ⓘ systematic development of bonding concepts ⓘ systematic development of reactivity principles ⓘ |
| field |
homogeneous catalysis
ⓘ
organometallic chemistry ⓘ transition metal chemistry ⓘ |
| focusesOn |
applications in homogeneous catalysis
ⓘ
bond activation processes ⓘ catalytic cycles ⓘ ligand effects in catalysis ⓘ principles of organometallic bonding ⓘ principles of organometallic reactivity ⓘ reaction coordinate analysis ⓘ transition metal–carbon bonds ⓘ |
| genre |
academic textbook
ⓘ
chemistry textbook ⓘ |
| intendedAudience |
advanced undergraduates
ⓘ
chemists working in catalysis ⓘ graduate students ⓘ researchers in organometallic chemistry ⓘ |
| isAbout |
homogeneous catalytic cycles
ⓘ
relationship between bonding and catalysis ⓘ transition metal mediated transformations ⓘ |
| mainSubject |
catalytic reaction mechanisms
ⓘ
metal–ligand bonding ⓘ organometallic bonding ⓘ organometallic reactivity ⓘ organotransition metal complexes ⓘ |
| teaches |
beta-hydride elimination
ⓘ
electron counting methods ⓘ ligand substitution mechanisms ⓘ migratory insertion ⓘ molecular orbital description of metal complexes ⓘ oxidative addition ⓘ reductive elimination ⓘ |
| uses |
bonding models to rationalize reactivity
ⓘ
reaction mechanisms as organizing principle ⓘ |
How these facts were elicited
The pipeline generated the facts above by prompting gpt-5.1 with this entity's name + description and the instruction below.
Instruction
You are a knowledge base construction expert. Given a subject entity and a description of it, return factual statements that you know for the subject as a JSON list of dictionaries(triples), where keys must be "subject", "predicate" and "object". The number of facts may be very high, between 25 to 50 or more, for very popular subjects. For less popular subjects, the number of facts can be very low, like 5 or 10. # Requirements - If you don't know the subject at all, return an empty list. - If the subject is not a named entity, return an empty list. - Include at least one triple where predicate is "instanceOf". - Do not get too wordy. - Separate several objects into multiple triples with one object.
Input
Subject: Organotransition Metal Chemistry: From Bonding to Catalysis Description of subject: "Organotransition Metal Chemistry: From Bonding to Catalysis" is a comprehensive graduate-level textbook that systematically develops the principles of organometallic bonding and reactivity with a strong emphasis on their applications in homogeneous catalysis.
Referenced by (1)
Full triples — surface form annotated when it differs from this entity's canonical label.