gptkbp:instance_of
|
gptkb:chemical_compound
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gptkbp:activities
|
involves carbene intermediate
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gptkbp:application
|
synthesis of pharmaceuticals
synthesis of natural products
|
gptkbp:developed_by
|
1970s
|
gptkbp:discovered_by
|
gptkb:John_Pauson
Elias James Corey and Robert Ziegler
|
https://www.w3.org/2000/01/rdf-schema#label
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Corey– Ziegler– Pauson reaction
|
gptkbp:involves
|
gptkb:chemical_compound
alkyne
|
gptkbp:named_after
|
gptkb:Robert_Ziegler
gptkb:Elias_James_Corey
gptkb:John_Pauson
|
gptkbp:notable_recipients
|
gptkb:chemical_compound
metal salts
unreacted alkyne
|
gptkbp:produced_by
|
cyclopropane derivative
|
gptkbp:related_to
|
gptkb:Pauson–_Khand_reaction
cyclopropanation
|
gptkbp:safety_features
|
requires handling of toxic materials
requires high-pressure equipment
|
gptkbp:type
|
cyclopropanation reaction
|
gptkbp:used_in
|
organic synthesis
|
gptkbp:was_a_catalyst_for
|
gptkb:copper(II)_acetate
gptkb:nickel(II)_acetate
gptkb:rhodium(II)_acetate
|
gptkbp:was_a_response_to
|
high pressure
high temperature
transition metal catalyst
|
gptkbp:bfsParent
|
gptkb:Elias_James_Corey
|
gptkbp:bfsLayer
|
5
|