Corey– Diels– Alder reaction
GPTKB entity
Statements (60)
| Predicate | Object |
|---|---|
| gptkbp:instance_of |
gptkb:chemical_compound
|
| gptkbp:can_be_performed_under |
thermal conditions
catalytic conditions |
| gptkbp:can_be_used_to_synthesize |
gptkb:Android
alkaloids |
| gptkbp:can_create |
natural products
six-membered rings |
| gptkbp:can_involve |
electron-poor dienophile
electron-rich diene |
| gptkbp:developed_by |
gptkb:Elias_James_Corey
|
| gptkbp:first_described_by |
1953
|
| https://www.w3.org/2000/01/rdf-schema#label |
Corey– Diels– Alder reaction
|
| gptkbp:involves |
diene
dienophile |
| gptkbp:involves_a_transition_state |
gptkb:true
|
| gptkbp:is_a_concerted_reaction |
gptkb:true
|
| gptkbp:is_a_method_for_forming |
C-C bonds
|
| gptkbp:is_a_reaction_between |
two unsaturated compounds
|
| gptkbp:is_a_reaction_that_forms |
cycloadducts
|
| gptkbp:is_essential_for |
organic chemistry
|
| gptkbp:is_regioselective |
gptkb:true
|
| gptkbp:is_reversible |
under certain conditions
|
| gptkbp:is_stereospecific |
gptkb:true
|
| gptkbp:is_used_in |
polymer chemistry
synthesis of complex organic molecules |
| gptkbp:is_used_in_the_synthesis_of |
gptkb:pharmaceuticals
|
| gptkbp:key_feature |
total synthesis
|
| gptkbp:named_after |
gptkb:Elias_James_Corey
gptkb:Otto_Diels Corey and Diels |
| gptkbp:produces |
cyclohexene derivatives
|
| gptkbp:type |
cycloaddition
|
| gptkbp:type_of |
pericyclic reaction
|
| gptkbp:was_a_catalyst_for |
transition metals
Lewis acids |
| gptkbp:was_a_response_to |
used in nanotechnology
regioselective used in green chemistry used in material science used in organometallic chemistry performed in solvent-free conditions stereoselective used in asymmetric synthesis used in combinatorial chemistry used in supramolecular chemistry used in the synthesis of dendrimers used in the synthesis of polymers used in polymerization reactions chemoselective performed in aqueous conditions performed under microwave irradiation performed under photochemical conditions used in the synthesis of block copolymers used in the synthesis of copolymers used in the synthesis of graft copolymers used in the synthesis of nanocomposites used in the synthesis of oligomers used in the synthesis of star polymers |
| gptkbp:bfsParent |
gptkb:Elias_James_Corey
|
| gptkbp:bfsLayer |
5
|